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The addition of electron donating methoxy groups leads to a

The addition of electron donating methoxy groups leads to a

Using time resolved photoelectron spectroscopy, it is shown that the dynamics are facilitated by a bound valence state of the anion. The addition of electron donating methoxy groups leads to a reduced ability to access the ground state compared to para benzoquinone. Both time resolved dynamics and calculations provide a rationale for these observations..

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steriods Formation of the 3 (3′ ) adduct is kinetically preferred but the 1 (1′ ) adduct is thermodynamically more stable. In media of high basicity the 1:2 adduct with alkoxide addition at the 1 and 1′ positions is observed. For HNS a third interaction occurs which may be alkoxide addition at the olefinic bond. steriods

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